Armaroli – Publications
Armaroli – Publications

Armaroli – Publications

Papers 2015-2024

P. Vecchi, F. Ruani, M. Mazzanti, Q. R. Loague, R. Mazzaro, F. Boscherini, B. Ventura, G. J. Meyer, N. Armaroli, S. Caramori, L. Pasquini 

“Impact of Co-Fe Overlayers on Charge Carrier Dynamics at WO3/BiVO4Heterojunctions: A Picosecond-to-Second Spectroscopic Analysis”

ACS Energy Lett. 20249, 2193-2200


N. Armaroli, E. Bandini, A. Barbieri  

“Hydrogen as an Energy Carrier: Constraints and Opportunities”

Pure App. Chem. 2024, 96, 479-485


M. Dumartin, S. Abid, Y. Gisbert, N. Saffon-Merceron, S. Gao, N. Armaroli, B. Ventura, C. Kammerer. G. Rapenne  

“ Synthesis of symmetric and dissymmetric star-shaped pentaarylcyclopentadienyl Ru(II) complexes containing styryl-BODIPY fragments ”

Chem. Lett. 2024, 53, upad003 


T.-A. Phan, M. Jouffroy, D. Matt, N. Armaroli, A. Saavedra Moncada, E. Bandini, B. Delavaux-Nicot, J. F. Nierengarten, D. Armspach

“Stabilization of Luminescent Mononuclear Three-Coordinate CuI Complexes by Two Distinct Cavity-Shaped Diphosphanes Obtained from a Single α-Cyclodextrin Precursor”

Chem. Eur. J. 2024, 30, e202302750


J. Tu, D. Veclani, F. Monti, A. Mazzanti, L. Sambri, N. Armaroli, A. Baschieri  

“Unexpected reactivity of cyclometalated iridium(III) dimers. Direct synthesis of a mononuclear luminescent complex”

Dalton Trans. 2023, 52, 14867–14879


B. Ventura, D. Veclani, A. Venturini, N. Armaroli, M. Baroncini, P. Ceroni, M. Marchini  

“Elucidating the Excited State Behavior of Pyridyl Pyridinium Systems via Computational and Transient Absorption studies of Tetrahedral Multichromophoric Arrays and their Model Compounds”

Chem. Eur. J. 2023, 29, e202301853


A. Edo-Osagie, D. Serillon, F. Ruani, X. Barril, C. Gourlaouen, N. Armaroli, B. Ventura, H.-P. Jacquot de Rouville, V. Heitz  

“Multi-Responsive Eight-State Bis(acridinium-Zn(II) porphyrin)Receptor”

J. Am. Chem. Soc. 2023, 145, 10691−10699


F. Ruani, A. Edo-Osagie, H.-P. Jacquot de Rouville, V. Heitz, B. Ventura, N. Armaroli 

“Photophysical characterization of a bisacridinium-diphenylporphyrin conjugate ”

J. Porphyrins Phthalocyanines 2023, 27, 569–575


J. Cerezo, S. Gao, N. Armaroli, F. Ingrosso, G. Prampolini, F. Santoro, B. Ventura, M. Pastore

“Non-Phenomenological Description of the Time-Resolved Emission in Solution with Quantum–Classical Vibronic Approaches—Application to Coumarin C153 in Methanol”

Molecules 2023, 28, 3910


A. Baschieri, F. Aleotti, E. Matteucci, L. Sambri, M. Mancinelli, A. Mazzanti, E. Leoni, N. Armaroli, F. Monti

“Pyridyl-1,2-azaborine Ligand for Phosphorescent Neutral Iridium(III) Complexes”

Inorg. Chem. 2023, 62, 2456


T.-A. Phan, N. Armaroli, A. Saavedra Moncada, E. Bandini, B. Delavaux-Nicot, J. F. Nierengarten, D. Armspach

“Stable Luminescent [Cu(NN)(PP)]+ Complexes Incorporating a b-Cyclodextrin-based Diphosphane Ligand with Metal Confining Properties”

Angew. Chem. Int. Ed. Engl. 2023, 62, e202214638


D. Veclani, A. Melchior, A. Llobet, N. Armaroli, A. Venturini

“Analysis of the role of the pH in the anchoring of alkylphosphonic acid on a TiO2 surface: A DFTB study”

Comput. Mater. Sci. 2023219, 111997


N. Armaroli, C. Carraro, P. Cazzola, E. Cherchi, M. Tanelli, M. Tavoni, A. Tilche, M. Torsello

“The road ahead: how to reduce emissions and energy use for Italy’s transport sector”

Nat. Italy 2022, doi: 10.1038/d43978-022-00098-x


A. Di Girolamo, F. Monti, A. Mazzanti, E. Matteucci, N. Armaroli, L. Sambri, A. Baschieri

“4-Phenyl-1, 2, 3-triazoles as Versatile Ligands for Cationic Cyclometalated Iridium (III) Complexes”

Inorg. Chem. 202261, 8509–8520


N. Armaroli, A. Barbieri
“The hydrogen dilemma in Italy’s energy transition”
Nature Italy 2021, 10.1038/d43978-021-00109-3


M. Marchini, A. Luisa, G. Bergamini, N. Armaroli, B. Ventura, M. Baroncini, N. Demitri. E. Iengo, P. Ceroni
“Giant shape-persistent tetrahedral porphyrin system: light-induced charge separation”
Chem. Eur. J. 2021, 27, DOI: 10.1002/chem.202102135


S. Gao, Y. Gisbert, G. Erbland, S. Abid, C. Kammerer, A. Venturini, G. Rapenne, B. Ventura, N. Armaroli
“Photophysical properties of 1,2,3,4,5-pentaarylcyclopentadienyl hydrotris(indazolyl)borate ruthenium(II) complexes”
Phys. Chem. Chem. Phys. 2021, 23, 17049-17056


F. Monti, A. Baschieri, L. Sambri, N. Armaroli
“Excited-State Engineering in Heteroleptic Ionic Iridium(III) Complexes”
Acc. Chem. Res. 2021, 59, 1492-1505


A. Baschieri, L. Sambri, A. Mazzanti, A. Carlone, F. Monti, N. Armaroli
“Iridium(III) Complexes with Fluorinated Phenyl-tetrazoles as Cyclometalating Ligands: Enhanced Excited-State Energy and Blue Emission”
Inorg. Chem. 2020, 59, 16238–16250


S. Gao, B. Balan, K. Yoosaf, F. Monti, E. Bandini, A. Barbieri, N. Armaroli
“Highly efficient luminescent solar concentrators based on benzoheterodiazole dyes with large Stokes’ shifts”
Chem. Eur. J. 2020, 26, 11013-11023 – Hot paper on the Special Issue for the 8th EuChemS Conference


F. Monti, A. Barbieri, N. Armaroli
“Battery Electric Vehicles: Perspectives and Challenges”
Substantia 2019, 3(2) Suppl. 2 , 75-89 – Special Issue: An Energy Transition To Save The Planet


E. Matteucci, A. Baschieri, L. Sambri, F. Monti, E. Pavoni, E. Bandini, N. Armaroli
“Carbazole‐Terpyridine Donor‐Acceptor Dyads with Rigid π‐Conjugated Bridges”
ChemPlusChem 2019, 84, 1353-1365


J.-F. Nierengarten, I. Nierengarten, M. Holler, A. Sournia-Saquet, B. Delavaux-Nicot, E. Leoni, F. Monti, N. Armaroli
“Dinuclear Copper(I) Complexes Combining Bis(diphenylphosphanyl)acetylene with 1,10‐Phenanthroline Ligands”
Eur. J. Inorg. Chem. 2019, 2665-2673 – COVER PAGE ARTICLE


N. Armaroli
“In my element: Iridium”
Chem. Eur. J. 2019, 25, 5104


A. Baschieri, F. Monti, N. Armaroli, G. Mazzotti, L. Giorgini, L. Sambri, T. Benelli
“Luminescent methacrylic copolymers with side-chain cyclometalated iridium(III) complexes”
Dyes and Pigments 2019, 160, 188-197


E. Leoni, J. Mohanraj, M. Holler, M. Mohankumar, I. Nierengarten, F. Monti, A. Sournia-Saquet, B. Delavaux-Nicot, J.-F. Nierengarten, N. Armaroli
“Heteroleptic Cu(I) Complexes Prepared from Phenanthroline and Bis-Phosphine Ligands: Rationalization of the Photophysical and Electrochemical Properties”
Inorg. Chem. 2018, 57, 15537-15549


Y. Troyez, A. D. Finke, F. Silvestri, F. Monti, B. Ventura, C. Boudon, J.-P. Gisselbrecht, W. B. Schweizer, J.-P. Sauvage, N. Armaroli, F. Diederich
“Unconventional Synthesis of a Cu(I) Rotaxane with a Superacceptor Stopper: Ultrafast Excited-State Dynamics and Near-Infrared Luminescence”
Chem. Eur. J. 2018, 24, 10422-10433


M. Mohankumar, M. Holler, E. Meichsner, J.-F. Nierengarten, F. Niess, J.-P. Sauvage, B. Delavaux-Nicot, E. Leoni, F. Monti, J. M. Malicka, M. Cocchi, E. Bandini, N. Armaroli
“Heteroleptic Copper(I) Pseudorotaxanes Incorporating Macrocyclic Phenanthroline Ligands of Different Sizes”
J. Am. Chem. Soc. 2018, 140, 2336-2347


P.-H. Lanoe, J. Chan, A. Groue, G. Gontard, A. Jutand, M.-N. Rager, N. Armaroli, F. Monti, A. Barbieri, H. Amouri
“DCyclometalated N-heterocyclic carbene iridium(III) complexes with naphthalimide chromophores: a novel class of phosphorescent heteroleptic compounds”
Dalton Trans. 2018, 47, 3440-3451


E. Matteucci, A. Baschieri, A. Mazzanti, L. Sambri, J. Avila, A. Pertegas, H. J. Bolink, F. Monti, E. Leoni, N. Armaroli
“Anionic Cyclometalated Iridium(III) Complexes with a Bis-Tetrazolate Ancillary Ligand for Light-Emitting Electrochemical Cells”
Inorg. Chem. 2017, 56, 10584–10595


J. Mohanraj, A. Barbieri, N. Armaroli, M. Vizuete, F. Langa, B. Delavaux-Nicot, M. Vartanian, J. Iehl, U. Hahn, J.-F. Nierengarten
“Efficient Photoinduced Energy- and Electron-transfer in ZnII-Porphyrin / Fullerene Dyads with Interchromophoric Distance up to 2.6 nm and no Wire-like Connectivity”
Chem. Eur. J. 2017, 23, 14200-14212 – COVER PAGE ARTICLE


A. Gualandi, D. Mazzarella, A. Ortega Martinez, L. Mengozzi, F. Calcinelli, E. Matteucci, F. Monti, N. Armaroli, L. Sambri, P. G. Cozzi
“Photocatalytic Radical Alkylation of Electrophilic Olefins by Benzylic and Alkylic Zinc-Sulfinates”
ACS Catal. 2017, 7, 5357-5362


A. Nano, M. P. Gullo, B. Ventura, A. Barbieri, N. Armaroli, R. Ziessel
“Color-Tunable Heterodinuclear Pt(II)/B(III) and Pt(II)/Ir(III) Arrays with N^O-julolidine Ligands”
Inorg. Chem. 2017, 56, 4807-4817


A. Gualandi, E. Matteucci, F. Monti, A. Baschieri, N. Armaroli, L. Sambri, P. G. Cozzi
“Photoredox Radical Conjugate Addition of Dithiane-2-carboxylate Promoted by an Iridium(III)phenyltetrazole Complex: A Formal Radical Methylation of Michael Acceptors”
Chem. Sci. 2017, 8, 1613-1620


T. Miletić, E. Pavoni, V. Trifiletti, A. Rizzo, A. Listorti, S. Colella, N. Armaroli, D. Bonifazi
“Covalently Functionalized SWCNTs as Tailored p-type Dopants for Perovskite Solar Cells”
ACS Appl. Mater. Interfaces 2016, 8, 27966-27973


N. Armaroli, V. Balzani
“Solar Electricity and Solar Fuels: Status and Perspectives in the Context of the Energy Transition”
Chem. Eur. J. 2016, 22, 32-57
Read the related interview on Chemistry Views: “The Sun-Powered Civilization”


A. Baschieri, F. Monti, E. Matteucci, A. Mazzanti , A. Barbieri, N. Armaroli, L. Sambri
“A Mesoionic Carbene as Neutral Ligand for Phosphorescent Cationic Ir(III) Complexes”
Inorg. Chem. 2016, 55, 7912-7919


A. Barbieri, E. Bandini, F. Monti, V. K. Praveen, N. Armaroli
“The Rise of Near Infrared Emitters: Organic Dyes, Porphyrinoids and Transition Metal Complexes”
Top. Curr. Chem. 2016, 374, 47


P.-H. Lanoë, J. Chan, G. Gontard, F. Monti, N. Armaroli, A. Barbieri, H. Amouri
“Deep-Red Phosphorescent Iridium(III) Complexes with Chromophoric N-Heterocyclic Carbene Ligands: Design, Photophysical Properties, and DFT Calculations”
Eur. J. Inorg. Chem. 2016, 1631-1634


N. Armaroli, H. J. Bolink
“Luminescence: The Never-Ending Story”
Top. Curr. Chem. 2016, 374, 44


L. Ðordevic, T. Marangoni, F. De Leo, I. Papagiannouli, P. Aloukos, S. Couris, E. Pavoni, F. Monti, N. Armaroli, M. Prato, D. Bonifazi
“[60]Fullerene–porphyrin [n]-pseudorotaxanes: self-assembly, photophysics and third-order NLO responses”
Phys. Chem. Chem. Phys. 2016, 18, 11858-11868


F. Monti, A. Venturini, A. Nenov, F. Tancini, A. D. Finke, F. Diederich, N. Armaroli
“Anilino-Substituted Multicyanobuta-1,3-diene Electron Acceptors: TICT Molecules with Accessible Conical Intersections”
J. Phys. Chem. A 2015, 119, 10677-10683


A. Kremer, C. Aurisicchio, F. De Leo, B. Ventura, J. Wouters, N. Armaroli, A. Barbieri, D. Bonifazi
“Walking down the chalcogenic group of the periodic table: from singlet to triplet organic emitters”
Chem. Eur. J. 2015, 21, 15377-15387


F. Monti, A. Baschieri, E. Matteucci, A. Mazzanti, L. Sambri, A. Barbieri, N. Armaroli
“A chelating diisocyanide ligand for cyclometalated Ir(III) complexes with strong and tunable luminescence”
Faraday Discuss. 2015, 185, 233-248


L. Đorđević, T. Marangoni, T. Miletić, J. Rubio-Magnieto, J. Mohanraj, H. Amenitsch, D. Pasini, N. Liaros, S. Couris, N. Armaroli, M. Surin, D. Bonifazi
“Solvent Molding of Organic Morphologies Made of Supramolecular Chiral Polymers”
J. Am. Chem. Soc. 2015, 137, 8150-8160


F. Monti, M. G. I. La Placa, N. Armaroli, R. Scopelliti, M. Grätzel, Md. K. Nazeeruddin, F. Kessler
“Cationic Iridium(III) Complexes with Two Carbene-Based Cyclometalating Ligands: Cis Versus Trans Isomers”
Inorg. Chem. 2015, 54, 3031-3042


A. Nano, M. P. Gullo, B. Ventura, N. Armaroli, A. Barbieri, R. Ziessel
“Panchromatic luminescence from julolidine dyes exhibiting excited state intramolecular proton transfer”
Chem. Commun. 2015, 51, 3351-3354


A. Kremer, E. Bietlot, A. Zanelli, J. M. Malicka, N. Armaroli, D. Bonifazi
“Versatile Bisethynyl[60]fulleropyrrolidine Scaffolds for Mimicking Artificial Light-Harvesting Photoreaction Centers”
Chem. Eur. J. 2015, 21, 1108-1117